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B Stabilized phosphorescence spectra of monomer MDP and you will MND in 2-methyltetrahydrofuran (1 × 10−5 M) from the 77 K (top), along with polymer PDA and you may PNA in the area-temperature (RT) (bottom) pleased on the 280 and 360 nm. C Polymer film excitation–phosphorescence mapping away from PDA (top) and PNA (bottom) in the area-heat. Age Pure transition orbitals on the lower triplet alter away from MDP and you can MND in the gaseous condition. It is rather property value noting your own homochiral Roentgen-BINAP and you will S-BINAP shown refined variations in the newest spectral molds of a single’s circularly polarized luminescence (CPL) indicators shown into the Additional Fig. As well, nevertheless they introduced additional phosphorescent targets the new polymer chain in order to get ready RTP device that have tunable phosphorescence emission out of blue to help you red-colored .

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